Thursday, March 18, 2010

Optical mineralogy

Optical mineralogy is the study of minerals and rocks by measuring their optical properties. Most commonly, rock and mineral samples are prepared as thin sections or grain mounts for study in the laboratory with a petrographic microscope. Optical mineralogy is used to identify the mineralogical composition of geological materials in order to help reveal their origin and evolution.

Some of the properties and techniques used include:

* Refractive index
* Birefringence
* Michel-Lévy Interference colour chart
* Pleochroism
* Extinction angle
* Conoscopic interference pattern (Interference figure)
* Becke line test
* Optical relief
* Sign of elongation (Length fast vs. length slow)
* Wave plate
History

William Nicol, whose name is associated with the creation of the Nicol prism, seems to have been the first to prepare thin slices of mineral substances, and his methods were applied by Henry Thronton Maire Witham (1831) to the study of plant petrifactions. This method, of such far-reaching importance in petrology, was not at once made use of for the systematic investigation of rocks, and it was not until 1858 that Henry Clifton Sorby pointed out its value. Meanwhile the optical study of sections of crystals had been advanced by Sir David Brewster and other physicists and mineralogists and it only remained to apply their methods to the minerals visible in rock sections.[1]
[edit] Sections

A good rock-section should be about one-thousandth of an inch (30 microns) in thickness, and is by no means very difficult to make. A thin splinter of the rock, about as large as a halfpenny may be taken; it should be as fresh as possible and free from obvious cracks. By grinding it on a plate of planed steel or cast iron with a little fine carborundum it is soon rendered flat on one side and is then transferred to a sheet of plate glass and smoothed with the very finest emery till all minute pits and roughnesses are removed and the surface is a uniform plane. The rock-chip is then washed, and placed on a copper or iron plate which is heated by a spirit or gas lamp. A microscopic glass slip is also warmed on this plate with a drop of viscous natural Canada balsam on its surface. The more volatile ingredients of the balsam are dispelled by the heat, and when that is accomplished the smooth, dry, warm rock is pressed firmly into contact with the glass plate so that the film of balsam intervening may be as thin as possible and free from air-bubbles. The preparation is allowed to cool and then the rock chip is again ground down as before, first with carborundum and, when it becomes transparent, with fine emery till the desired thickness is obtained. It is then cleaned, again heated with a little more balsam, and covered with a cover glass. The labor of grinding the first surface may be avoided by cutting off a smooth slice with an iron disk armed with crushed diamond powder. A second application of the slitter after the first face is smoothed and cemented to the glass will in expert hands leave a rock-section so thin as to be already transparent. In this way the preparation of a section may require only twenty minutes.[1]
[edit] Microscope
Photomicrograph of a volcanic sand grain; upper picture is plane-polarized light, bottom picture is cross-polarized light, scale box at left-center is 0.25 millimeter.

The microscope employed is usually one which is provided with a rotating stage beneath which there is a polarizer, while above the objective or the eyepiece an analyzer is mounted; alternatively the stage may be fixed and the polarizing and analyzing prisms may be capable of simultaneous rotation by means of toothed wheels and a connecting-rod. If ordinary light and not polarized light is desired, both prisms may be withdrawn from the axis of the instrument; if the polarizer only is inserted the light transmitted is plane polarized; with both prisms in position the slide is viewed in cross-polarized light, also known as "crossed nicols." A microscopic rock-section in ordinary light, if a suitable magnification (say 30) be employed, is seen to consist of grains or crystals varying in color, size and shape.[1]
[edit] Characters of minerals

Some minerals are colorless and transparent (quartz, calcite, feldspar, muscovite, etc.), others are yellow or brown (rutile, tourmaline, biotite), green (diopside, hornblende, chlorite), blue (glaucophane), pink (garnet), etc. The same mineral may present a variety of colors, in the same or different rocks, and these colors may be arranged in zones parallel to the surfaces of the crystals. Thus tourmaline may be brown, yellow, pink, blue, green, violet, grey, or colorless, but every mineral has one or more characteristic, most common tints. The shapes of the crystals determine in a general way the outlines of the sections of them presented on the slides. If the mineral has one or more good cleavages they will be indicated by systems of cracks. The refractive index is also clearly shown by the appearance of the section, which are rough, with well-defined borders if they have a much stronger refraction than the medium in which they are mounted. Some minerals decompose readily and become turbid and semi-transparent (e.g. feldspar); others remain always perfectly fresh and clear (e.g. quartz), others yield characteristic secondary products (such as green chlorite after biotite). The inclusions in the crystals (both solid and fluid) are of great interest; one mineral may enclose another, or may contain spaces occupied by glass, by fluids or by gases.[1]
Microstructure

Lastly the structure of the rock, that is to say, the relation of its components to one another, is usually clearly indicated, whether it be fragmented or massive; the presence of glassy matter in contradistinction to a completely crystalline or "holo-crystalline" condition; the nature and origin of organic fragments; banding, foliation or lamination; the pumiceous or porous structure of many lavas; these and many other characters, though often not visible in the hand specimens of a rock, are rendered obvious by the examination of a microscopic section. Many refined methods of observation may be introduced, such as the measurement of the size of the elements of the rock by the help of micrometers; their relative proportions by means of a glass plate ruled in small squares; the angles between cleavages or faces seen in section by the use of the rotating graduated stage, and the estimation of the refractive index of the mineral by comparison with those of different mounting media.[1]
Pleochroism
Main article: Pleochroism

Further information is obtained by inserting the polarizer and rotating the section. The light vibrates now only in one plane, and in passing through doubly refracting crystals in the slide, is, speaking generally, broken up into rays, which vibrate at right angles to one another. In many colored minerals such as biotite, hornblende, tourmaline, chlorite, these two rays have different colors, and when a section containing any of these minerals is rotated the change of color is often very striking. This property, known as "pleochroism" is of great value in the determination of rock-making minerals.

Pleochroism is often especially intense in small spots which surround minute enclosures of other minerals, such as zircon and epidote, these are known as "pleochroic halos."[1]
Double refraction

If the analyzer be now inserted in such a position that it is crossed relatively to the polarizer the field of view will be dark where there are no minerals, or where the light passes through isotropic substances such as glass, liquids and cubic crystals. All other crystalline bodies, being doubly refracting, will appear bright in some position as the stage is rotated. The only exception to this rule is provided by sections which are perpendicular to the optic axes of birefringent crystals; these remain dark or nearly dark during a whole rotation, and as will be seen later, their investigation is of special importance.[1]
Extinction

The doubly refracting mineral sections, however, will in all cases appear black in certain positions as the stage is rotated. They are said to go "extinct" when this takes place. If we note these positions we may measure the angle between them and any cleavages, faces or other structures of the crystal by means of the rotating stage. These angles are characteristic of the system to which the mineral belongs and often of the mineral species itself (see Crystallography). To facilitate measurement of extinction angles various kinds of eyepieces have been devised, some having a stereoscopic calcite plate, others with two or four plates of quartz cemented together; these are often found to give more exact results than are obtained by observing merely the position in which the mineral section is most completely dark between crossed nicols.

The mineral sections when not extinguished are not only bright but are colored and the colors they show depend on several factors, the most important of which is the strength of the double refraction. If all the sections are of the same thickness as is nearly true of well-made slides, the minerals with strongest double refraction yield the highest polarization colors. The order in which the colors are arranged in what is known as Newton's scale, the lowest being dark grey, then grey, white, yellow, orange, red, purple, blue and so on. The difference between the refractive indexes of the ordinary and the extraordinary ray in quartz is .009, and in a rock-section about 1/500 of an inch thick this mineral gives grey and white polarization colours; nepheline with weaker double refraction gives dark grey; augite on the other hand will give red and blue, while calcite with the stronger double refraction will appear pinkish or greenish white. All sections of the same mineral, however, will not have the same color; it was stated above that sections perpendicular to an optic axis will be nearly black, and, in general, the more nearly any section approaches this direction the lower its polarization colors will be. By taking the average, or the highest color given by any mineral, the relative value of its double refraction can be estimated; or if the thickness of the section be precisely known the difference between the two refractive indexes can be ascertained. If the slides be thick the colors will be on the whole higher than in thin slides.

It is often important to find out whether of the two axes of elasticity (or vibration traces) in the section is that of greater elasticity (or lesser refractive index). The quartz wedge or selenite plate enables us to do this. Suppose a doubly refracting mineral section so placed that it is "extinguished"; if now is rotated through 45 degrees it will be brightly illuminated. If the quartz wedge be passed across it so that the long axis of the wedge is parallel to the axis of elasticity in the section the polarization colors will rise or fall. If they rise the axes of greater elasticity in the two minerals are parallel; if they sink the axis of greater elasticity in the one is parallel to that of lesser elasticity in the other. In the latter case by pushing the wedge sufficiently far complete darkness or compensation will result. Selenite wedges, selenite plates, mica wedges and mica plates are also used for this purpose. A quartz wedge also may be calibrated by determining the amount of double refraction in all parts of its length. If now it be used to produce compensation or complete extinction in any doubly refracting mineral section, we can ascertain what is the strength of the double refraction of the section because it is obviously equal and opposite to that of a known part of the quartz wedge.

A further refinement of microscopic methods consists of the use of strongly convergent polarized light (konoscopic methods). This is obtained by a wide angled achromatic condenser above the polarizer, and a high power microscopic objective. Those sections are most useful which are perpendicular to an optic axis, and consequently remain dark on rotation. If they belong to uniaxial crystals they show a dark cross or convergent light between crossed nicols, the bars of which remain parallel to the wires in the field of the eyepiece. Sections perpendicular to an optic axis of a biaxial mineral under the same conditions show a dark bar which on rotation becomes curved to a hyperbolic shape. If the section is perpendicular to a "bisectrix" (see Crystallography) a black cross is seen which on rotation opens out to form two hyperbolas, the apices of which are turned towards one another. The optic axes emerge at the apices of the hyperbolas and may be surrounded by colored rings, though owing to the thinness of minerals in rock sections these are only seen when the double refraction of the mineral is strong. The distance between the axes as seen in the field of the microscope depends partly on the axial angle of the crystal and partly on the numerical aperture of the objective. If it is measured by means of eye-piece micrometer, the optic axial angle of the mineral can be found by a simple calculation. The quartz wedge, quarter mica plate or selenite plate permit the determination of the positive or negative character of the crystal by the changes in the color or shape of the figures observed in the field. These operations are precisely similar to those employed by the mineralogist in the examination of plates cut from crystals. It is sufficient to point out that the petrological microscope in its modern development is an optical instrument of great precision, enabling us to determine physical constants of crystallized substances as well as serving to produce magnified images like the ordinary microscope. A great variety of accessory apparatus has been devised to fit it for these special uses.
Examination of rock powders

Although rocks are now studied principally in microscopic sections the investigation of fine crushed rock powders, which was the first branch of microscopic petrology to receive attention, is by no means discontinued. The modern optical methods are perfectly applicable to transparent mineral fragments of any kind. Minerals are almost as easily determined in powder as in section, but it is otherwise with rocks, as the structure or relation of the components to one another, which is an element of great importance in the study of the history and classification or rocks, is almost completely destroyed by grinding them to powder.

Petroleum geology

Sedimentary basin analysis

Petroleum geology is principally concerned with the evaluation of seven key elements in sedimentary basins:
A structural trap, where a fault has juxtaposed a porous and permeable reservoir against an impermeable seal. Oil (shown in red) accumulates against the seal, to the depth of the base of the seal. Any further oil migrating in from the source will escape to the surface and seep.

* Source
* Reservoir
* Seal
* Trap
* Timing
* Maturation
* Migration

In general, all these elements must be assessed via a limited 'window' into the subsurface world, provided by one (or possibly more) exploration wells. These wells present only a 1-dimensional segment through the Earth and the skill of inferring 3-dimensional characteristics from them is one of the most fundamental in petroleum geology. Recently, the availability of cheap and high quality 3D seismic data (from reflection seismology) has greatly aided the accuracy of such interpretation. The following section discusses these elements in brief. For a more in-depth treatise, see the second half of this article below.

Evaluation of the source uses the methods of geochemistry to quantify the nature of organic-rich rocks which contain the precursors to hydrocarbons, such that the type and quality of expelled hydrocarbon can be assessed.

The reservoir is a porous and permeable lithological unit or set of units that holds the hydrocarbon reserves. Analysis of reservoirs at the simplest level requires an assessment of their porosity (to calculate the volume of in situ hydrocarbons) and their permeability (to calculate how easily hydrocarbons will flow out of them). Some of the key disciplines used in reservoir analysis are the fields of stratigraphy, sedimentology, and reservoir engineering.

The seal, or cap rock, is a unit with low permeability that impedes the escape of hydrocarbons from the reservoir rock. Common seals include evaporites, chalks and shales. Analysis of seals involves assessment of their thickness and extent, such that their effectiveness can be quantified.

The trap is the stratigraphic or structural feature that ensures the juxtaposition of reservoir and seal such that hydrocarbons remain trapped in the subsurface, rather than escaping (due to their natural buoyancy) and being lost.

Analysis of maturation involves assessing the thermal history of the source rock in order to make predictions of the amount and timing of hydrocarbon generation and expulsion.

Finally, careful studies of migration reveal information on how hydrocarbons move from source to reservoir and help quantify the source (or kitchen) of hydrocarbons in a particular area.
Major subdisciplines in petroleum geology

Several major subdisciplines exist in petroleum geology specifically to study the seven key elements discussed above.
Analysis of source rocks

In terms of source rock analysis, several facts need to be established. Firstly, the question of whether there actually is any source rock in the area must be answered. Delineation and identification of potential source rocks depends on studies of the local stratigraphy, palaeogeography and sedimentology to determine the likelihood of organic-rich sediments having been deposited in the past.

If the likelihood of there being a source rock is thought to be high, the next matter to address is the state of thermal maturity of the source, and the timing of maturation. Maturation of source rocks (see diagenesis and fossil fuels) depends strongly on temperature, such that the majority of oil generation occurs in the 60° to 120°C range. Gas generation starts at similar temperatures, but may continue up beyond this range, perhaps as high as 200°C. In order to determine the likelihood of oil/gas generation, therefore, the thermal history of the source rock must be calculated. This is performed with a combination of geochemical analysis of the source rock (to determine the type of kerogens present and their maturation characteristics) and basin modelling methods, such as back-stripping, to model the thermal gradient in the sedimentary column.
Analysis of reservoir

The existence of a reservoir rock (typically, sandstones and fractured limestones) is determined through a combination of regional studies (i.e. analysis of other wells in the area), stratigraphy and sedimentology (to quantify the pattern and extent of sedimentation) and seismic interpretation. Once a possible hydrocarbon reservoir is identified, the key physical characteristics of a reservoir that are of interest to a hydrocarbon explorationist are its porosity and permeability. Traditionally, these were determined through the study of hand specimens, contiguous parts of the reservoir that outcrop at the surface and by the technique of formation evaluation using wireline tools passed down the well itself. Modern advances in seismic data acquisition and processing have meant that seismic attributes of subsurface rocks are readily available and can be used to infer physical/sedimentary properties of the rocks themselves.

Oceanography

Oceanography (compound of the Greek words ωκεανός meaning "ocean" and γράφω meaning "to write"), also called oceanology or marine science, is the branch of Earth science that studies the ocean. It covers a wide range of topics, including marine organisms and ecosystem dynamics; ocean currents, waves, and geophysical fluid dynamics; plate tectonics and the geology of the sea floor; and fluxes of various chemical substances and physical properties within the ocean and across its boundaries. These diverse topics reflect multiple disciplines that oceanographers blend to further knowledge of the world ocean and understanding of processes within it: biology, chemistry, geology, meteorology, and physics.
Branches

The study of oceanography is divided into a number of branches:

* Biological oceanography, or marine biology, is the study of the plants, animals and microbes of the oceans and their ecological interaction with the ocean;
* Chemical oceanography, or marine chemistry, is the study of the chemistry of the ocean and its chemical interaction with the atmosphere;
* Geological oceanography, or marine geology, is the study of the geology of the ocean floor including plate tectonics;
* Physical oceanography, or marine physics, studies the ocean's physical attributes including temperature-salinity structure, mixing, waves, internal waves, surface tides, internal tides, and currents. Of particular interest is the behavior of sound (acoustical oceanography), light (optical oceanography) and radio waves in the ocean.

These branches reflect the fact that many oceanographers are first trained in the exact sciences or mathematics and then focus on applying their interdisciplinary knowledge, skills and abilities to oceanography.[1]

Data derived from the work of Oceanographers is used in marine engineering, in the design and building of oil platforms, ships, harbours, and other structures that allow us to use the ocean safely.[2]

Oceanographic data management is the discipline ensuring that oceanographic data both past and present are available to researchers.
History

Man first began to acquire knowledge of the waves and currents of the seas and oceans in pre-historic times. Observations on tides are recorded by Aristotle and Strabo. Early modern exploration of the oceans was primarily for cartography and mainly limited to its surfaces and of the creatures that fishermen brought up in nets, though depth soundings by lead line were taken.
Map of the Gulf Stream by Benjamin Franklin, 1769-1770. Courtesy of the NOAA Photo Library.

Although Juan Ponce de Leon in 1513 first identified the Gulf Stream, and the current was well-known to mariners, Benjamin Franklin made the first scientific study of it and gave it its name. Franklin measured water temperatures during several Atlantic crossings and correctly explained the Gulf Stream's cause. Franklin and Timothy Folger printed the first map of the Gulf Stream in 1769-1770.[3][4]

When Louis Antoine de Bougainville, who voyaged between 1766 and 1769, and James Cook, who voyaged from 1768 to 1779, carried out their explorations in the South Pacific, information on the oceans themselves formed part of the reports. James Rennell wrote the first scientific textbooks about currents in the Atlantic and Indian oceans during the late 18th and at the beginning of 19th century. Sir James Clark Ross took the first modern sounding in deep sea in 1840, and Charles Darwin published a paper on reefs and the formation of atolls as a result of the second voyage of HMS Beagle in 1831-6. Robert FitzRoy published a report in four volumes of the three voyages of the Beagle. In 1841–1842 Edward Forbes undertook dredging in the Aegean Sea that founded marine ecology.

As first superintendent of the United States Naval Observatory (1842–1861) Matthew Fontaine Maury devoted his time to the study of marine meteorology, navigation, and charting prevailing winds and currents. His Physical Geography of the Sea, 1855 was the first textbook of oceanography. Many nations sent oceanographic observations to Maury at the Naval Observatory, where he and his colleagues evaluated the information and gave the results worldwide distribution. [5]

The steep slope beyond the continental shelves was discovered in 1849. The first successful laying of transatlantic telegraph cable in August 1858 confirmed the presence of an underwater "telegraphic plateau" mid-ocean ridge. After the middle of the 19th century, scientific societies were processing a flood of new terrestrial botanical and zoological information. European natural historians began to sense the lack of more than anecdotal knowledge of the oceans.

In 1871, under the recommendations of the Royal Society of London, the British government sponsored an expedition to explore world's oceans and conduct scientific investigations. Under that sponsorship the Scots Charles Wyville Thompson and Sir John Murray launched the Challenger expedition (1872–1876). The results of this were published in 50 volumes covering biological, physical and geological aspects. 4417 new species were discovered.

Other European and American nations also sent out scientific expeditions (as did private individuals and institutions). The first purpose built oceanographic ship, the "Albatros" was built in 1882. The four-month 1910 North Atlantic expedition headed by Sir John Murray and Johan Hjort was at that time the most ambitious research oceanographic and marine zoological project ever, and led to the classic 1912 book The Depths of the Ocean.

Oceanographic institutes dedicated to the study of oceanography were founded. In the United States, these included the Scripps Institution of Oceanography in 1892, Woods Hole Oceanographic Institution in 1930, Virginia Institute of Marine Science in 1938, Lamont-Doherty Earth Observatory at Columbia University, and the School of Oceanography at University of Washington. In Britain, there is a major research institution: National Oceanography Centre, Southampton which is the successor to the Institute of Oceanography. In Australia, CSIRO Marine and Atmospheric Research, known as CMAR, is a leading center. In 1921 the International Hydrographic Bureau (IHB) was formed in Monaco.
Ocean currents (1911)

In 1893 Fridtjof Nansen allowed his ship "Fram" to be frozen in the Arctic ice. As a result he was able to obtain oceanographic data as well as meteorological and astronomical data. The first international organization of oceanography was created in 1902 as the International Council for the Exploration of the Sea.

The first acoustic measurement of sea depth was made in 1914. Between 1925 and 1927 the "Meteor" expedition gathered 70,000 ocean depth measurements using an echo sounder, surveying the Mid atlantic ridge. The Great Global Rift, running along the Mid Atlantic Ridge, was discovered by Maurice Ewing and Bruce Heezen in 1953 while the mountain range under the Arctic was found in 1954 by the Arctic Institute of the USSR. The theory of seafloor spreading was developed in 1960 by Harry Hammond Hess. The Ocean Drilling Project started in 1966. Deep sea vents were discovered in 1977 by John Corlis and Robert Ballard in the submersible "Alvin".

In the 1950s Auguste Piccard invented the bathyscaphe and used the "Trieste" to investigate the ocean's depths. The nuclear submarine Nautilus made the first journey under the ice to the North Pole in 1958. In 1962 there was the first deployment of FLIP (Floating Instrument Platform), a 355 foot spar buoy.

Then in 1966, the U.S. Congress created a National Council for Marine Resources and Engineering Development. NOAA was put in charge of exploring and studying all aspects of Oceanography in the USA. It also enabled the National Science Foundation to award Sea Grant College funding to multi-disciplinary researchers in the field of oceanography.[6][7]

From the 1970s there has been much emphasis on the application of large scale computers to oceanography to allow numerical predictions of ocean conditions and as a part of overall environmental change prediction. An oceanographic buoy array was established in the Pacific to allow prediction of El Niño events.

1990 saw the start of the World Ocean Circulation Experiment (WOCE) which continued until 2002. Geosat seafloor mapping data became available in 1995.

In 1942 Sverdrup and Fleming published "The Ocean" which was a major landmark. "The Sea" (in three volumes covering physical oceanography, seawater and geology) edited by M.N. Hill was published in 1962 while the "Encyclopedia of Oceanography" by Rhodes Fairbridge was published in 1966.
Ocean and atmosphere connections

The study of the oceans is intimately linked to understanding global climate changes, potential global warming and related biosphere concerns. The atmosphere and ocean are linked because of evaporation and precipitation as well as thermal flux (and solar insolation). Wind stress is a major driver of ocean currents while the ocean is a sink for atmospheric carbon dioxide.

Our planet is invested with two great oceans; one visible, the other invisible; one underfoot, the other overhead; one entirely envelopes it, the other covers about two thirds of its surface.

Volcanology

Volcanology (also spelled vulcanology) is the study of volcanoes, lava, magma, and related geological, geophysical and geochemical phenomena. The term volcanology is derived from the Latin word vulcan, which means the Roman god of fire.
Volcanologist examining tephra horizons in south-central Iceland.

A volcanologist is a person who studies the formation of volcanoes, and their current and historic eruptions. Volcanologists frequently visit volcanoes, especially active ones, to observe volcanic eruptions, collect eruptive products including tephra (such as ash or pumice), rock and lava samples. One major focus of enquiry is the prediction of eruptions; there is currently no accurate way to do this, but predicting eruptions, like predicting earthquakes, could save many lives.

History of volcanology

Volcanology has an extensive history. The earliest known recording of a volcanic eruption may be on a wall painting dated to about 7000 B.C.E. found at the Neolithic site at Çatal Höyük (now known as Çatalhöyük), in Anatolia, Turkey. This painting has been interpreted as a depiction of an erupting volcano, with a cluster of houses below shows a twin peaked volcano in eruption, with a town at its base (though archaeologists now question this interpretation [1]). The volcano may be either Hasan Dağ, or its smaller neighbour, Melendiz Dağ. [2]
[edit] Mythical explanations

The classical world of Greece and the early Roman Empire explained volcanoes as the work of the gods as science and alchemy had no explanation for their existence. Grecian myths and tales tell of Atlantis, a fabled island which sank into the sea. Plato (428-348 B.C.) told of the disappearance of a vast island and its powerful civilization, the Atlanteans, in two of his dialogues, Critias and Timaeus. It is now considered that the island of Thera, now Santorini, in the Aegean Sea, was destroyed by a tremendous series of volcanic explosions around 1620 B.C., with ash falls of up to a foot deep recorded in Turkey. The explosion of Thera sent colossal tsunamis, estimated at 100 feet height, racing across the Aegean, and the southern coast of Crete. Other recordings of the Thera eruption spawned Greek myths, namely the Deucalion, in which Poseidon, god of the sea, took revenge upon Zeus by inundating Attica, Argolis, Salonika, Rhodes and the coast of Lycia (Turkey) to Sicily.

Greeks also considered that Hephaestus, the god of fire, sat below the volcano Etna, forging the weapons of Zeus. His minions, the cyclops with their single staring eye, may be an allegory to the round craters and cones of a volcano. Indeed, the Greek word used to describe volcanoes was etna, or hiera, after Heracles, the son of Zeus. The Roman poet Virgil, in interpreting the Greek mythos, held that the hero Enceladus was buried beneath Etna by the goddess Athena as punishment for disobeying the gods; the mountain's rumblings were his tormented cries, the flames his breath and the tremors his railing against the bars of his prison. Enceladus' brother Mimas was buried beneath Vesuvius by Hephaestus, and the blood of other defeated giants welled up in the Phlegrean Fields surrounding Vesuvius.

Tribal legends of volcanoes abound from the Pacific Ring of Fire and the Americas, usually invoking the forces of the supernatural or the divine to explain the violent outbursts of volcanoes. Taranaki and Tongariro, according to Māori mythology, were lovers who fell in love with Pihanga, and a spiteful jealous fight ensued. Māori will not to this day live between Tongariro and Taranaki for fear of the dispute flaring up again.
Greco-Roman science
Eruption of Vesuvius in 1822. The eruption of AD 79 would have appeared very similar.

The first attempt at a scientific explanation of volcanoes was undertaken by the Greek philosopher Empedocles (c. 490-430 B.C.), who saw the world divided into four elemental forces, of Earth, Air, Fire and Water. Volcanoes, Empedocles maintained, were the manifestation of Elemental Fire. Plato contended that channels of hot and cold waters flow in inexhaustible quantities through subterranean rivers. In the depths of the earth snakes a vast river of fire, the Pyriphlegethon, which feeds all the world's volcanoes. Aristotle considered underground fire as the result of "the...friction of the wind when it plunges into narrow passages."

Wind would play a key role in explanations of volcanoes until the 16th century. Lucretius, a Roman philosopher, claimed Etna was completely hollow and the fires of the underground driven by a fierce wind circulating near sea level. Ovid believed that the flame was fed from "fatty foods" and eruptions stopped when the food ran out. Vitruvius contended that sulfur, alum and bitumen fed the deep fires. Observations by Pliny the Elder noted the presence of earthquakes preceded an eruption; he died in the eruption of Vesuvius in 79 AD while investigating it at Stabiae. His nephew, Pliny the Younger gave detailed descriptions of the eruption in which his uncle died, attributing his death to the effects of toxic gases. Such eruptions have been named Plinian in honour of the two authors.
Christian mythology

The study of volcanology was not advanced much between the days of Plato and Hutton. The Christian world explained volcanoes by a multitude of prescientific notions, but it was also thought they were the work of Satan or the wrath of God, and only saintly miracles could avert their wrath. For this reason the relics of Saint Agatha were paraded in front of lava advancing on Catania in 253 A.D., and miraculously the lava clove in two (down two valleys) and spared the town. Unfortunately the relics of St. Agatha proved ineffective in 1669, with the loss of much of Catania to Etna's lava.

In 1660 the eruption of Vesuvius rained twinned pyroxene crystals and ash upon the nearby villages. The twinned pyroxene crystals resembled the crucifix and this was interpreted as the work of Saint Januarius. In Naples, the relics of St Januarius are paraded through town at every major eructation of Vesuvius. The register of these processions allowed British diplomat and amateur naturalist Sir William Hamilton to document Vesuvius' eruptions, one of the first few 'scientific' studies of the eruptive history of a volcano.
An aerial photo of Vesuvius
Renaissance observations

Renaissance descriptions of volcanoes vastly improved the state of knowledge, despite the resistance of the Church to scientific explorations of the natural world, especially those which were at odds with Biblical teachings. Nevertheless, nuées ardentes were described from the Azores in 1580. Georgius Agricola argued the rays of the sun, as later proposed by Descartes had nothing to do with volcanoes. Agricola believed vapor under pressure caused eruptions of 'mointain oil' and basalt.

Jesuit Athanasius Kircher (1602–1680) witnessed eruptions of Mount Etna and Stromboli, then visited the crater of Vesuvius and published his view of an Earth with a central fire connected to numerous others caused by the burning of sulfur, bitumen and coal.

Johannes Kepler considered volcanoes as conduits for the tears and excrement of the Earth, voiding bitumen, tar and sulfur. Descartes, pronouncing that God had created the Earth in an instant, declared he had done so in three layers; the fiery depths, a layer of water, and the air. Volcanoes, he said, were formed where the rays of the sun pierced the earth.

Science wrestled with the ideas of the combustion of pyrite with water, that rock was solidified bitumen, and with notions of rock being formed from water (Neptunism). Of the volcanoes then known, all were near the water, hence the action of the sea upon the land was used to explain volcanism.
Modern volcanology

Seismic observations are made using seismographs deployed near volcanic areas, watching out for increased seismicity during volcanic events, in particular looking for long period harmonic tremors which signal magma movement through volcanic conduits.[3]

Surface deformation monitoring includes the use of geodetic techniques such as leveling, tilt, strain, angle and distance measurements through tiltmeters, total stations and EDMs. This also includes GNSS observations and InSAR.[4][5] Surface deformation indicates magma upwelling: increased magma supply produces bulges in the volcanic center's surface.

Gas emissions may be monitored with equipment including portable ultra-violet spectrometers (COSPEC, now superseded by the miniDOAS) which analyzes the presence of volcanic gases such as sulfur dioxide; or by infra-red spectroscopy (FTIR). Increased gas emissions, and more particularly changes in gas compositions, may signal an impending volcanic eruption.

Temperature changes are monitored using thermometers and observing changes in thermal properties of volcanic lakes and vents which may indicate upcoming activity.

Other geophysical techniques (electrical, gravity and magnetic observations) include monitoring fluctuations and sudden change in resistivity, gravity anomalies or magnetic anomaly patterns which may indicate volcano-induced faulting and magma upwelling.

Stratigraphic analyses includes analyzing tephra and lava deposits and dating these to give volcano eruption patterns, with estimated cycles of intense activity and size of eruptions.

Glaciology

laciology (from Middle French dialect (Franco-Provençal): glace, "ice"; or Latin: glacies, "frost, ice"; and Greek: λόγος, logos, "speech" lit. "study of ice") is the study of glaciers, or more generally ice and natural phenomena that involve ice.

Glaciology is an interdisciplinary earth science that integrates geophysics, geology, physical geography, geomorphology, climatology, meteorology, hydrology, biology, and ecology. The impact of glaciers on humans adds the fields of human geography and anthropology. The presence of ice on Mars and Europa brings in an extraterrestrial component to the field.

Overview

Areas of study within glaciology include glacial history and the reconstruction of past glaciation. A glaciologist is a person who studies glaciers. Glaciology is one of the key areas of polar research. A glacier is an extended mass of ice formed from snow falling and accumulating over the years and moving very slowly, either descending from high mountains, as in valley glaciers, or moving outward from centers of accumulation, as in continental glaciers.
[edit] Types

There are two general categories of glaciation which glaciologists distinguish: alpine glaciation, accumulations or "rivers of ice" confined to valleys; and continental glaciation, unrestricted accumulations which once covered much of the northern continents.

* Alpine - ice flows down the valleys of mountainous areas and forms a tongue of ice moving towards the plains below. Alpine glaciers tend to make the topography more rugged, by adding and improving the scale of existing features such as large ravines called cirques and ridges where the rims of two cirques meet called arêtes.
* Continental - an ice sheet found today, only in high latitudes (Greenland/Antarctica), thousands of square kilometers in area and thousands of meters thick. These tend to smooth out the landscapes.

Zones of glaciers

* Accumulation, where the formation of ice is faster than its removal.
* Wastage or Ablation, where the sum of melting and evaporation (sublimation) is greater than the amount of snow added each year.

Movement

Ablation
wastage of the glacier through sublimation, ice melting and iceberg calving.
Ablation zone
Area of a glacier in which the annual loss of ice through ablation exceeds the annual gain from precipitation.
Arête
an acute ridge of rock where two cirques abut.
Bergshrund
crevasse formed near the head of a glacier, where the mass of ice has rotated, sheared and torn itself apart in the manner of a geological fault.
Cirque, corrie or cwm
bowl shaped depression excavated by the source of a glacier.
Creep
adjustment to stress at a molecular level.
Flow
movement (of ice) in a constant direction.
Fracture
brittle failure (breaking of ice) under the stress raised when movement is too rapid to be accommodated by creep. It happens for example, as the central part of a glacier movinges faster than the edges.
Horn
spire of rock formed by the headward erosion of a ring of cirques around a single mountain. It is an extreme case of an arête.
Plucking/Quarrying
where the adhesion of the ice to the rock is stronger than the cohesion of the rock, part of the rock leaves with the flowing ice.
Tarn
a lake formed in the bottom of a cirque when its glacier has melted.
Tunnel valley
The tunnel is that formed by hydraulic erosion of ice and rock below an ice sheet margin. The tunnel valley is what remains of it in the underlying rock when the ice sheet has melted.

Glacial deposits
Stratified

Outwash sand/gravel
from front of glaciers, found on a plain
Kettles
block of stagnant ice leaves a depression or pit
Eskers
steep sided ridges of gravel/sand, possibly caused by streams running under stagnant ice
Kames
stratified drift builds up low steep hills
Varves
alternating thin sedimentary beds (coarse and fine) of a proglacial lake. Summer conditions deposit more and coarser material and those of the winter, less and finer.

Unstratified

Till-unsorted
(glacial flour to boulders) deposited by receding/advancing glaciers, forming moraines, and drumlins
Moraines
(Terminal) material deposited at the end; (Ground) material deposited as glacier melts; (lateral) material deposited along the sides.
Drumlins
smooth elongated hills composed of till.
Ribbed moraines
large subglacial elongated hills transverse to former ice flow.

Monday, March 15, 2010

Seismology

Seismology (from Greek σεισμός, seismos, "earthquake"; and -λόγος, -logia, as a whole "Talking about earthquakes") is the scientific study of earthquakes and the propagation of elastic waves through the Earth. The field also includes studies of earthquake effects, such as tsunamis as well as diverse seismic sources such as volcanic, tectonic, oceanic, atmospheric, and artificial processes (such as explosions). A related field that uses geology to infer information regarding past earthquakes is paleoseismology. A recording of earth motion as a function of time is called a seismogram.

Seismic waves
Main article: Seismic wave

Earthquakes, and other sources, produce different types of seismic waves which travel through rock, and provide an effective way to image both sources and structures deep within the Earth. There are three basic types of seismic waves in solids: P-waves, S-waves (both body waves) and interface waves. The two basic kinds of surface waves (Rayleigh and Love) which travel along a solid-air interface, can be fundamentally explained in terms of interacting P- and/or S-waves.
Propagation of seismic wave in the ground and the effect of presence of land mine.

Pressure waves or Primary waves (P-waves), are longitudinal waves that travel at maximum velocity within solids and are therefore the first waves to appear on a seismogram.

S-waves, also called shear or secondary waves, are transverse waves that travel more slowly than P-waves and thus appear later than P-waves on a seismogram. Particle motion is perpendicular to the direction of wave propagation. Shear waves do not exist in fluids with essentially no shear strength, such as air or water.

Surface waves travel more slowly than P-waves and S-waves, but because they are guided by the surface of the Earth (and their energy is thus trapped near the Earth's surface) they can be much larger in amplitude than body waves, and can be the largest signals seen in earthquake seismograms. They are particularly strongly excited when the seismic source is close to the surface of the Earth, such as the case of a shallow earthquake or explosion.

For large enough earthquakes, one can observe the normal modes of the Earth. These modes are excited as discrete frequencies and can be observed for days after the generating event. The first observations were made in the 1960s as the advent of higher fidelity instruments coincided with two of the largest earthquakes of the 20th century - the 1960 Great Chilean earthquake and the 1964 Great Alaskan earthquake. Since then, the normal modes of the Earth have given us some of the strongest constraints on the deep structure of the Earth.

One of the earliest important discoveries (suggested by Richard Dixon Oldham in 1906 and definitively shown by Harold Jeffreys in 1926) was that the outer core of the Earth is liquid. Pressure waves (P-waves) pass through the core. Transverse or shear waves (S-waves) that shake side-to-side require rigid material so they do not pass through the outer core. Thus, the liquid core causes a "shadow" on the side of the planet opposite of the earthquake where no direct S-waves are observed. The reduction in P-wave velocity of the outer core also causes a substantial delay for P waves penetrating the core from the (seismically faster velocity) mantle.

Seismic waves produced by explosions or vibrating controlled sources are one of the primary methods of underground exploration in geophysics (in addition to many different electromagnetic methods such as induced polarization and magnetotellurics). Controlled source seismology has been used to map salt domes, faults, anticlines and other geologic traps in petroleum-bearing rocks, geological faults, rock types, and long-buried giant meteor craters. For example, the Chicxulub impactor, which is believed to have killed the dinosaurs, was localized to Central America by analyzing ejecta in the cretaceous boundary, and then physically proven to exist using seismic maps from oil exploration.

Using seismic tomography with earthquake waves, the interior of the Earth has been completely mapped to a resolution of several hundred kilometers. This process has enabled scientists to identify convection cells, mantle plumes and other large-scale features of the inner Earth.

Seismographs are instruments that sense and record the motion of the Earth. Networks of seismographs today continuously monitor the seismic environment of the planet, allowing for the monitoring and analysis of global earthquakes and tsunami warnings, as well as recording a variety of seismic signals arising from non-earthquake sources ranging from explosions (nuclear and chemical), to pressure variations on the ocean floor induced by ocean waves (the global microseism), to cryospheric events associated with large icebergs and glaciers. Above-ocean meteor strikes as large as ten kilotons of TNT, (equivalent to about 4.2 × 1013 J of effective explosive force) have been recorded by seismographs. A major motivation for the global instrumentation of the Earth with seismographs has been for the monitoring of nuclear testing.


One of the first attempts at the scientific study of earthquakes followed the 1755 Lisbon earthquake. Other especially notable earthquakes that spurred major developments in the science of seismology include the 1857 Basilicata earthquake, 1906 San Francisco earthquake, the 1964 Alaska earthquake and the 2004 Sumatra-Andaman earthquake. An extensive list of famous earthquakes can be found on the List of earthquakes page.
[edit] Earthquake prediction

Main article: Earthquake prediction

Forecasting a probable timing, location, magnitude and other important features of a forthcoming seismic event is called earthquake prediction. Most seismologists do not believe that a system to provide timely warnings for individual earthquakes has yet been developed, and many believe that such a system would be unlikely to give significant warning of impending seismic events. More general forecasts, however, are routinely used to establish seismic hazard. Such forecasts estimate the probability of an earthquake of a particular size affecting a particular location within a particular time span and they are routinely used in earthquake engineering.

Various attempts have been made by seismologists and others to create effective systems for precise earthquake predictions, including the VAN method. Such methods have yet to be generally accepted in the seismology community.

Hydrogeology

Hydrogeology (hydro- meaning water, and -geology meaning the study of the Earth) is the area of geology that deals with the distribution and movement of groundwater in the soil and rocks of the Earth's crust, (commonly in aquifers). The term geohydrology is often used interchangeably. Some make the minor distinction between a hydrologist or engineer applying themselves to geology (geohydrology), and a geologist applying themselves to hydrology (hydrogeology).

Introduction

Hydrogeology is an interdisciplinary subject; it can be difficult to account fully for the chemical, physical, biological and even legal interactions between soil, water, nature and society. The study of the interaction between groundwater movement and geology can be quite complex. Groundwater does not always flow in the subsurface down-hill following the surface topography; groundwater follows pressure gradients (flow from high pressure to low) often following fractures and conduits in circuitous paths. Taking into account the interplay of the different facets of a multi-component system often requires knowledge in several diverse fields at both the experimental and theoretical levels. This being said, the following is a more traditional introduction to the methods and nomenclature of saturated subsurface hydrology, or simply hydrogeology.
[edit] Hydrogeology in relation to other fields

Hydrogeology, as stated above, is a branch of the earth sciences dealing with the flow of water through aquifers and other shallow porous media (typically less than 450 m or 1,500 ft below the land surface.) The very shallow flow of water in the subsurface (the upper 3 m or 10 ft) is pertinent to the fields of soil science, agriculture and civil engineering, as well as to hydrogeology. The general flow of fluids (water, hydrocarbons, geothermal fluids, etc.) in deeper formations is also a concern of geologists, geophysicists and petroleum geologists. Groundwater is a slow-moving, viscous fluid (with a Reynolds number less than unity); many of the empirically derived laws of groundwater flow can be alternately derived in fluid mechanics from the special case of Stokes flow (viscosity and pressure terms, but no inertial term).

The mathematical relationships used to describe the flow of water through porous media are the diffusion and Laplace equations, which have applications in many diverse fields. Steady groundwater flow (Laplace equation) has been simulated using electrical, elastic and heat conduction analogies. Transient groundwater flow is analogous to the diffusion of heat in a solid, therefore some solutions to hydrological problems have been adapted from heat transfer literature.

Traditionally, the movement of groundwater has been studied separately from surface water, climatology, and even the chemical and microbiological aspects of hydrogeology (the processes are uncoupled). As the field of hydrogeology matures, the strong interactions between groundwater, surface water, water chemistry, soil moisture and even climate are becoming more clear.
[edit] Definitions and material properties
Main article: Aquifer

One of the main tasks a hydrogeologist typically performs is the prediction of future behavior of an aquifer system, based on analysis of past and present observations. Some hypothetical, but characteristic questions asked would be:

* Can the aquifer support another subdivision?
* Will the river dry up if the farmer doubles his irrigation?
* Did the chemicals from the dry cleaning facility travel through the aquifer to my well and make me sick?
* Will the plume of effluent leaving my neighbor's septic system flow to my drinking water well?

Most of these questions can be addressed through simulation of the hydrologic system (using numerical models or analytic equations). Accurate simulation of the aquifer system requires knowledge of the aquifer properties and boundary conditions. Therefore a common task of the hydrogeologist is determining aquifer properties using aquifer tests.

In order to further characterize aquifers and aquitards some primary and derived physical properties are introduced below. Aquifers are broadly classified as being either confined or unconfined (water table aquifers), and either saturated or unsaturated; the type of aquifer affects what properties control the flow of water in that medium (e.g., the release of water from storage for confined aquifers is related to the storativity, while it is related to the specific yield for unconfined aquifers).
[edit] Hydraulic head
Main article: Hydraulic head

Changes in hydraulic head (h) are the driving force which causes water to move from one place to another. It is composed of pressure head (ψ) and elevation head (z). The head gradient is the change in hydraulic head per length of flowpath, and appears in Darcy's law as being proportional to the discharge.

Hydraulic head is a directly measurable property that can take on any value (because of the arbitrary datum involved in the z term); ψ can be measured with a pressure transducer (this value can be negative, e.g., suction, but is positive in saturated aquifers), and z can be measured relative to a surveyed datum (typically the top of the well casing). Commonly, in wells tapping unconfined aquifers the water level in a well is used as a proxy for hydraulic head, assuming there is no vertical gradient of pressure. Often only changes in hydraulic head through time are needed, so the constant elevation head term can be left out (Δh = Δψ).

A record of hydraulic head through time at a well is a hydrograph or, the changes in hydraulic head recorded during the pumping of a well in a test are called drawdown.
[edit] Porosity
Main article: Porosity

Porosity (n) is a directly measurable aquifer property; it is a fraction between 0 and 1 indicating the amount of pore space between unconsolidated soil particles or within a fractured rock. Typically, the majority of groundwater (and anything dissolved in it) moves through the porosity available to flow (sometimes called effective porosity). Permeability is an expression of the connectedness of the pores. For instance, an unfractured rock unit may have a high porosity (it has lots of holes between its constituent grains), but a low permeability (none of the pores are connected). An example of this phenomenon is pumice, which, when in its unfractured state, can make a poor aquifer.

Porosity does not directly affect the distribution of hydraulic head in an aquifer, but it has a very strong effect on the migration of dissolved contaminants, since it affects groundwater flow velocities through an inversely proportional relationship.
[edit] Water content
Main article: water content

Water content (θ) is also a directly measurable property; it is the fraction of the total rock which is filled with liquid water. This is also a fraction between 0 and 1, but it must also be less than or equal to the total porosity.

The water content is very important in vadose zone hydrology, where the hydraulic conductivity is a strongly nonlinear function of water content; this complicates the solution of the unsaturated groundwater flow equation.
[edit] Hydraulic conductivity
Main article: Hydraulic conductivity

Hydraulic conductivity (K) and transmissivity (T) are indirect aquifer properties (they cannot be measured directly). T is the K integrated over the vertical thickness (b) of the aquifer (T=Kb when K is constant over the entire thickness). These properties are measures of an aquifer's ability to transmit water. Intrinsic permeability (κ) is a secondary medium property which does not depend on the viscosity and density of the fluid (K and T are specific to water); it is used more in the petroleum industry.
[edit] Specific storage and specific yield
Main article: Specific storage

Specific storage (Ss) and its depth-integrated equivalent, storativity (S=Ssb), are indirect aquifer properties (they cannot be measured directly); they indicate the amount of groundwater released from storage due to a unit depressurization of a confined aquifer. They are fractions between 0 and 1.

Specific yield (Sy) is also a ratio between 0 and 1 (Sy ≤ porosity) and indicates the amount of water released due to drainage from lowering the water table in an unconfined aquifer. Typically Sy is orders of magnitude larger than Ss. Often the porosity or effective porosity is used as an upper bound to the specific yield.
[edit] Contaminant transport properties

Often we are interested in how the moving groundwater water will move dissolved contaminants around (the sub-field of contaminant hydrogeology). The contaminants can be man-made (e.g., petroleum products, nitrate or Chromium) or naturally occurring (e.g., arsenic, salinity). Besides needing to understand where the groundwater is flowing, based on the other hydrologic properties discussed above, there are additional aquifer properties which affect how dissolved contaminants move with groundwater.

Dispersivity (αL, αT) is an empirical factor which quantifies how much contaminants stray away from the path of the groundwater which is carrying it. Some of the contaminants will be "behind" or "ahead" the mean groundwater, giving rise to a longitudinal dispersivity (αL), and some will be "to the sides of" the pure advective groundwater flow, leading to a transverse dispersivity (αT).

Dispersivity is actually a factor which represents our lack of information about the system we are simulating. There are many small details about the aquifer which are being averaged when using a macroscopic approach (e.g., tiny beds of gravel and clay in sand aquifers), they manifest themselves as an apparent dispersivity. Because of this, α is often claimed to be dependent on the length scale of the problem — the dispersivity found for transport through 1 m³ of aquifer is different than that for transport through 1 cm³ of the same aquifer material.

Hydrodynamic dispersion (D) is a positive physical parameter which describes the molecule-scale movement of solute away from the mean flow; it is a result of Brownian motion. This is the same mechanism as dye uniformly spreading out in a still bucket of water. The dispersion coefficient is typically quite small (typically orders of magnitude smaller than α), and can often be considered negligible (unless groundwater flow velocities are extremely low, as they are in clay aquitards).

It is important not to confuse hydrodynamic dispersion with dispersivity, as the former is a physical phenomenon and the latter is an empirical factor which is cast into a similar form as dispersion, because we already know how to solve that problem.
[edit] Governing equations
[edit] Darcy's Law
Main article: Darcy's law

Darcy's law is a Constitutive equation (empirically derived by Henri Darcy, in 1856) that states the amount of groundwater discharging through a given portion of aquifer is proportional to the cross-sectional area of flow, the hydraulic head gradient, and the hydraulic conductivity.
[edit] Groundwater flow equation
Main article: Groundwater flow equation

The groundwater flow equation, in its most general form, describes the movement of groundwater in a porous medium (aquifers and aquitards). It is known in mathematics as the diffusion equation, and has many analogs in other fields. Many solutions for groundwater flow problems were borrowed or adapted from existing heat transfer solutions.

It is often derived from a physical basis using Darcy's law and a conservation of mass for a small control volume. The equation is often used to predict flow to wells, which have radial symmetry, so the flow equation is commonly solved in polar or cylindrical coordinates.

The Theis equation is one of the most commonly used and fundamental solutions to the groundwater flow equation; it can be used to predict the transient evolution of head due to the effects of pumping one or a number of pumping wells.

The Thiem equation is a solution to the steady state groundwater flow equation (Laplace's Equation). Unless there are large sources of water nearby (a river or lake), true steady-state is rarely achieved in reality.